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Two things I'd like to point out in regards to the episode you're looking for.

Firstly, I think the episode you're looking for is called "When You've Got to Go!". Secondly, I recall the episode being a HUGE favorite among creators of YouTube Poops, as I've noticed several YouTube Poops of the episode floating around; they would have to have gotten the episode somewhere to be able to make a YouTube Poop of it, so the episode itself might still be out there, likely on a (possibly out-of-print) VHS or DVD release.